Synthesis of Catena-bis(μ-bromo)-(O-methyl-N-phenylthiocarbamate)-dicopper(I) and Its Reactivity towards PAr3 (Ar = Ph, p-Tol)
نویسندگان
چکیده
In order to investigate the coordination chemistry of O-alkyl N-aryl thiocarbamate ligands toward coinage metals, CuBr was reacted with one equivalent MeOC(=S)N(H)Ph L in MeCN solution afford 1D-polymeric title compound [{Cu(μ2-Br)2Cu}{μ2-MeOC(=S)N(H)Ph}2]n CP1. Compound 1 characterized by IR spectroscopy and an elemental analysis. The formation a polymeric 1D ribbon built upon μ2-bridging bromido thione via C=S bond ascertained single-crystal X-ray diffraction study performed at 100 K. presence PAr3 (Ar = Ph, p-Tol), polymer chain broken yield mononuclear complexes [(Ar3P)2Cu{MeOC(=S)N(H)Ph}Br] C1 C2.
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ژورنال
عنوان ژورنال: Molbank
سال: 2023
ISSN: ['1422-8599']
DOI: https://doi.org/10.3390/m1655